Journal of Liaoning Petrochemical University
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Preparation of Oxidized Wax Emulsion
CHEN Peng,Liu Shu-xin, JI Ling-xian,WANG De, CONG Yu-feng, HUANG Wei1
Abstract381)      PDF (627KB)(231)      
Self-made oxidized wax was adopted to develop oxidized wax emulsion in this experiment, and the effect of emulsifiers amount, emulsification temperature, stirring speed and emulsification time on emulsion performance were investigated, and finally the formulation of complex emulsifiers and the emulsification technology were determined. The results show that the first grade oxidized wax emulsion, which is milk white and has good stability and dispersity, can be prepared when the HLB value of surfactants is 12.0, reaction temperature is 85 ℃, stirring speed is 800 r/min and reaction time is 35 min
2012, 32 (4): 21-23.
Preparation of Nitrogen-Containing Borate Ester as Lubricant Additives
JI Ling-xian, CHEN Peng, WANG De, CONG Yu-feng, HUANG Wei
Abstract424)      PDF (223KB)(395)      
Borate esters were prepared as anti-wear lubricants additives from stearic acid, diethanolamine and boric acid and characterized by infrared spectroscopy. Their optimum preparation conditions were determined by examining molecular ratio of reactants, amount of sodium hydroxide[KG*3]and[KG*3]so[KG*3]on.[KG*3]The[KG*3]experimental[KG*3]results[KG*3]show[KG*2]that[KG*2]the[KG*2]yield[KG*2]of[KG*2]borate[KG*2]esters[KG*2]can[KG*2]reach 43.33% under the optimum conditions: mole ratio of stearic acid, diethanolamine to boric acid 1.0∶1.1∶1.0, reaction temperature 105~110 ℃, reaction time 11 h. At the meanwhile, the effect of adding amount of lubricant additives on anti-wear performance of the lubricant base oil agents was also studied and find that when the mass fraction of nitrogen-containing borate ester 0.25% was adding in the liquid paraffin, PB value can reach 697.9 N, minimum wear scar diameter is 0.49 mm, the friction coefficient reduces by 0.017 as compared with that of liquid paraffin oil.